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Regioselective nitration of anilines with fe(no3)3·9h2o as a promoter and a nitro source

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Regioselective nitration of anilines with Fe(NO3)3·9H2O as a promoter and a nitro source†

* Corresponding authors

a School of Chemical Engineering và Light Industry, Guangdong University of Technology, Guangzhou, china E-mail: gaoyang

An efficient Fe(NO3)3·9H2O promoted ortho-nitration reaction of aniline derivatives has been developed. This reaction may go through a nitrogen dioxide radical (NO2˙) intermediate, which is generated by the thermal decomposition of iron(III) nitrate. The practicality of the present method using nontoxic và inexpensive iron reagents has been shown by the broad substrate scope và applications.

Regioselective nitration of anilines with Fe(NO3)3·9H2O as a promoter and a nitro source

Y. Gao, Y. Mao, B. Zhang, Y. Zhan and Y. Huo, Org. Biomol. Chem., 2018,16, 3881 DOI: 10.1039/C8OB00841H

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